🧲 Field Service

Free Iron Testing

Free iron testing identifies free iron on metal surfaces, most often on nickel and stainless steel, where surface contamination makes materials more corrosion-prone and shortens their service life.

Category

Field / On-Site

Methods

Ferroxyl · Copper sulfate

Materials

Nickel · stainless steel

Detects

Surface iron contamination

What it is

Free iron testing is used to identify free iron on a metal surface. This test is mainly performed on nickel and stainless steel, where iron contamination left from fabrication, tooling, or handling can compromise an otherwise corrosion-resistant surface.

Why it matters

The presence of free iron on a metal surface makes the material more corrosion-prone and reduces its lifespan. Testing verifies material quality and enables more accurate predictions about how long a component will perform in service.

Testing methods

Ferroxyl test

When ferroxyl (potassium ferricyanide) is in the presence of free iron on the surface of a metal, it reacts and changes to a blue color. This method detects even minimal surface contamination and is highly versatile.

Copper sulfate test

Copper sulfate acts as a less sensitive alternative to the ferroxyl test. When free iron is present, copper deposits create a bronze-colored sheen that persists after rinsing. However, it cannot be used on low-chromium stainless steels or certain other alloys.

Choosing a method: the ferroxyl test picks up even trace contamination and suits the widest range of alloys, while the copper sulfate test offers a simpler check where its sensitivity and alloy limits are acceptable.

How we deliver it

PMI Specialists employs experienced field technicians who perform these tests with precision and effectiveness as part of our field services offering, bringing surface-cleanliness verification to your site.

Case gallery

Free iron testing

Need to confirm your surfaces are iron-free?

Tell us the alloy and the application. Our field technicians perform the right free iron test on-site and report a clear, defensible result.